This page contains the GCSE AQA Chemistry Atomic Structure Questions and their answers for revision and understanding Atomic structure.This page also contains the link to the notes and video for the revision of this topic.
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1a As Elements on the left side of the periodic table are metals and on the right side are non-metals, we can classify them as:-
Metals: Barium Ba, Vanadium V, mercury, Hg, potassium, K, uranium, U
Non-Metals: Phosphorus, krypton, Kr.
b Hydrogen should be classified as a metal. Although hydrogen has 1s1 of electronic configuration, it does not show any of the properties that resemble alkaline metals. Therefore, hydrogen is not a metal. However, it shows many properties that resemble a non metal. Hydrogen forms covalent compounds, does not easily form cations and exists as a diatomic molecule. Therefore, it is considered non-metallic.
2 When we mix two elements together we can separate them quite easily by physical means but when two elements are chemically combined in a compound they are difficult to separate as compound is composed of two different atoms connected by strong chemical bonds that keep the atoms very tight. Therefore, they are very difficult to separate from the two elements mixed together. On the other hand mixtures are held together by physical means and no chemical bond is involved. Mixtures can be easily separated by physical means. Chemical bonds are difficult to separate and needs large amounts of energy to overcome the force of attraction in a chemical bond.
Diagram to explain the difference between an element and a compound
Source: Wikimedia Commons
An element contains a single type of atom, with a unique number of protons, neutrons and electrons.
A compound contains more than one type of atom, chemically combined to form a new substance.
Sourc: Wikimedia Commons
In the example above one atom of oxygen and two atoms of hydrogen elements joined to form water which is a compounds
4 The basic structure of an atom includes a small and relatively massive nucleus, which contains protons and neutrons .
Outside the nucleus there are energy levels (also called shells), which contain one or more electrons. Energy levels are often called electron shells.
Neutrons have the highest mass and have no charge. Protons have a slightly smaller mass than neutrons and are positively charged. The electrons have almost no mass and are negatively charged. Electrons move around the nucleus in energy levels.
Source: Wikimedia Commons
3.Latin words from which the symbols of these metallic elements are derived are :-
Sodium, Na – Natrium.
Gold, Au : Aurum.
Lead, Pb: Plumbum.
Potassium , K : Kalium.
6 The compound formula provides information on the number of atoms of each element in a molecule. From the chemical formula of carbon dioxide, we can see that it contains a carbon atom and 2 oxygen atoms.
1a All symbol equations must be balanced according to the law of mass conservation. According to the law of mass conservation, in a chemical reaction, the mass of the products must be equal to the mass of the reagents. Therefore, the equations must be balanced with the same number of moles of reagents and products on both sides.
b.MgCO3 (s) → MgO (s) + CO2 (g).
2Na(s) + 2H2O(l) → 2NaOH(aq) + H2(g).
A compound consists of the atoms of two or more elements that are chemically linked together. Since atoms always come together in the same proportion, the composition of a compound is always the same.
A mixture consists of two or more substances that are physically mixed in different proportions. It often retains many of the properties of its components, and the components can be separated from each other by physical means. For example, water is a compound that contains 2 hydrogen atoms and an oxygen atom chemically combined to form the H2O water molecule.
Source: Wikimedia Commons
1a. To separate a mixture of ethanol and water, we can use a process known as fractional distillation. This technique is based on the fact that the compounds in the mixture have different boiling points. We know that ethanol boils at a lower temperature than water, ethanol evaporates while most of the water remains a liquid. Then we can separate the ethanol and water mixture through this process. The boiling point of ethanol is 78 degrees and the water is 100 degrees. If the temperature is kept at about 80 degrees, all the ethanol will evaporate and collect. The water will remain in the flask.
Source: Wikimedia Commons
In distillation the solution forms steam before reaching the boiling point. In that case a fractionating column with glass beads is useful. Substances with a higher boiling point condense in colder glass beads and drip back into the flask. In this case, the water vapor will cool down in the glass beads and drip backwards. Substances with the lowest boiling point will continue to rise and pass to the condenser, cool and collected. In fractional distillation of ethanol, ethanol will raise first and collected and water will be left behind.
Components in the mixture are separated on the basis of solubility of
different components of the mixture in a suitable solvent.A capillary tube is used to spot the mixture on the chromatography paper. The paper is put inside a solvent and the solvent is allowed to run up the
chromatography paper. The component of the mixture which is more soluble in the solvent will
travel greater distance and will leave its mark near the top.
The component which is less soluble will have a mark near the bottom.
1.The greater the solubility of a substance in a solvent, the greater the distance traveled by a substance. In the chromatogram, substance B travels on paper higher than substance A, which means that substance B is more soluble in the solvent propanone of substance A.
Liquid | Boling point in °C |
Water | 100 |
Ethanol | 78 |
propanol | 97 |
When the boiling points of the two liquids in the mixture are close together, generally a difference of less than 40 degrees Celsius, fractional distillation is more efficient. The aforementioned liquids have a boiling point very close to each other, so it is not possible to separate them by simple distillation.
Fractional distillation completes several simple distillations in a single apparatus. In fractional distillation, the mixture is boiled in a fractionated column, a long tube that allows the liquid to evaporate and condense several times as it affects the colder air every time it moves towards the column. Crude oil is separated into its various components by fractional distillation.
C Atoms are solid spheres that cannot be split into simpler particles.
Lime is calcium Oxide and Soda is carbon dioxide in water.
In the Thomson model, the atom is composed of electrons surrounded by a positively charged soup to balance the negative charges of the electrons, like the “prunes” negatively charged surrounded by a positively charged “pudding”.
The 1904 Thomson model was denied by the 1909 gold leaf experiment by Hans Geiger and Ernest Marsden.
Source: Wikimedia Commons
Rutherford tested Thomson’s hypothesis by inventing his “gold foil” experiment. Rutherford reasoned that if Thomson’s model was correct, then the mass of the atom extended throughout the atom. So if you shoot alpha particles at high speed (helium nuclei) at an atom, there would be very little to bypass alpha particles. He decided to try this with a thin film of gold atoms. As expected, most of the alpha particles passed through the gold leaf, but to his surprise some alpha particles bounced almost directly backwards.
Therefore, he suggested that the atom has a dense center of positive charge called the nucleus and the orbits of the electrons around the nucleus.
Neutrons have no electrical charge; they are neutral.
These properties are summarised in the table showing the location, relative charge and relative mass of three subatomic particles
Particle | Relative mass | Relative charge | Location |
Proton | 1 | +1 | In the nucleus at the centre of the atom |
Neutron | 1 | 0 | In the nucleus at the centre of the atom |
Electron | 1/2000
-= 0.0005 | -1 | Revolves around the nucleus in the shells |
1 a) Protons: 5 , Neutrons: 6 , Electrons: 5
He
3. a. The electronic structure of potassium is 2,8,8,
b. A potassium atom has 1 electron in its highest energy level
4. The element in Figure 3 is phosphorus and the symbol is P
5.a. All elements of group 1 react in a similar way with oxygen as they all have one electron in their outermost layer. Since they have the same amount of electrons in their outermost layer, they react in a similar way. All group one elements reacts with oxygen to form metal oxides which forms alkali when dissolved in water.
b.Word equations for the reactions of lithium, sodium and potassium with oxygen:-
For lithium:
4Li(s)+O2 (g)→2Li2O(s)
For sodium:
4Na(s)+O2 (g)→2Na2O(s)
For potassium:
4K(s)+O2(g)→ 2K2O(s)
Alkali metals + chlorine → alkali metal chloride
The word and chemical equations for the reaction between lithium and chlorine are:
Lithium + chlorine → lithium chloride
2Li (s) + Cl2 (g) → 2LiCl (s)
Word and chemical equations for the reaction that produces sodium chloride are:
Sodium + chlorine → sodium chloride
2Na (s) + Cl2 (g) → 2NaCl (s)
(ii). The maximum number of electrons that each of the first two energy level or shells occupy
b (i) The overall charge on a atom is zero. Atom is neutral because an atom has Same number of protons (+) and electrons (–). So charges cancel out.
(ii) Atom can become an ion with a +2 charge by Losing two electrons. Loosing two electrons will leave the atoms with two more positive charges than negative charges so overall charge will be 2+.
(iii) The atomic number (also called the proton number) is the number of protons in an atom.
The mass number (also called the nucleon number) is the total number of protons and neutrons in an atom.
Mixture | Compound | |
Composition | Variable composition – you can vary the amount of each substance in a mixture. | Definite composition – you cannot vary the amount of each element in a compound. |
Joined or not | The different substances are not chemically joined together. | The different elements are chemically joined together. |
Properties | Each substance in the mixture keeps its own properties. | The compound has properties different from the elements it contains. |
Separation | Each substance is easily separated from the mixture. | It can only be separated into its elements using chemical reactions. |
Examples | Air, sea water, most rocks. | Water, carbon dioxide, magnesium oxide, sodium chloride |
(ii) A precipitate of lead iodide from the solution of lead nitrate and sodium iodide can be separated by filtration, as they precipitate is insoluble in the solution so can be collected in the filter paper and dried.
(iii) Water from the solution of potassium chloride can be separated by (simple) distillation, as water has a lower boiling point of 100 degrees so can be evaporated and passed through the condenser and collected.
(iv) Ethanol from the mixture of water and ethanol can be collected by fractional distillation as the boiling points are too close so ethanol will be evaporated first and collected. Water will be boiled at lower temperature, hit the glass beads and come back to the flask.
Gas: fluorine, xenon;
liquid: bromine;
solid: caesium, strontium.
Bromine = Br; caesium = Cs; fluorine = F; strontium = Sr; xenon = Xe.
Non-metals: bromine, fluorine, xenon;
metals: caesium, strontium
(i) Fluorine Atom
2, 7
2, 8
iii. Neon has at atomic number of 10 so Neon atoms contain 10 protons.
vii. Electron structure of the Neon atom is 2,8
viii. The special property of the electronic structure of Neon and the other elements in its group is that they have complete outer shells of electrons.
b.I. 88 Protons are present in the nucleus of each radium atom.
iI. Since radium belongs to group 2, radium atom has 2 electrons in its outermost shell. Group 2.
iii. Radium belongs to group 2 which is on the left side of the periodic table so radium is a metal.
20 p, 20 n, 18 e.
01.2. Since the salt solution in figure 1 is the run off after filtration so the word that best describes it is a Filtrate.
01.3. Sand becomes the residue in Figure 1 as sand is insoluble in water. The sand particles being insoluble in water and greater in size than the holes of the filter paper are trapped in the filter paper and are separated from the runoff solution.
01.4. From the solution in Step 3 the student can get dry salt crystals by evaporation the solution. The water will evaporate crystallizing the salt crystals. The salt crystals can then be dried and collected.
01.5. Since Mixtures have no fixed composition the student could not have predicted the mass of dry salt crystals obtained.
02.1. In figure 2 the pencil line is completely immersed in the solvent. This will result in the complete dissolution of the ink in the solvent without any separation. In an actual chromatography set up the solvent should run up and dissolve the ink components as the solvent travel up.
02.2. The line in chromatography paper should be drawn with the pencil as pencil does not dissolve in the solvent so it will not interfere with the results.
02.3. In Figure 3, the green ink has separated into blue and yellow spot so we can conclude that the green ink is a mixture of blue and yellow spot.
02.4. Yellow dye move further up the paper as The yellow dye is more soluble in the solvent than the blue dye so it has travelled the greater distance.
03.1. In Result 1 very few alpha particles repelled backwards so it shows that: atoms have nuclei at the centre with dense positive charge at the centre. Rest of the space is empty so the alpha particles passed straight through and the deflection was at the centre only.
In Result 2 most of the alpha particles went straight through the gold foil so it shows that: most of an atom is empty space or hollow.
103.2. The Similarities between the isotopes of chlorine are :-
Both isotopes have the same number of protons, electrons and atomic number. Their proton number, electron number and atomic number is 17..
Differences between the isotopes have chlorine are :-
Cl35 has 18 neutrons and Cl 37 has 20 neutrons. Chlorine 35 has the mass number of 35 and chlorine 37 has the mass number of 37.
03.3. Isotopes of chlorine has similar chemical properties as both isotopes have the same number of electrons and electronic configuration and Chemical properties depend on the electron configuration.
03.4 The relative atomic mass is a (weighted) average. Since the atomic mass average is closer to 35 than 37 so it means there must be more of chlorine–35 than 37.
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AQA GCSE Chemistry C1 Atomic Structure Revision Notes .This page contains the detailed and easy notes for AQA GCSE Chemistry C1
Atomic Structure and Mixtures for revision and understanding Atomic Structure and Mixtures.
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AQA GCSE Chemistry C1 Atomic Structure :-
History of Atoms
John Dalton | J.J Thomson | Rutherford | Neil Bohr | James Chadwick |
Early 1800s | 1800 end | 1911 | 1914 | 1932 |
Discovered Atoms | Discovered Electrons | Discovered Nucleus | Gave the idea of Electronic shells | Discovered Neutrons |
Plum Pudding Model | Alpha Scattering Experiment |
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Plum pudding model says that atom is the sphere of the positive charge the positive charge is equally distributed and in this sphere of the positive charge the electrons are embedded as raisins and give the plum pudding model and according to him the electron the positive were similar therefore atom is neutral.
Alpha Scattering Experiment – Geiger and Marsden –Radioactive particles
Dense, positively charged particles (called alpha particles) were fired at the thinnest piece of gold foil.
Most of the alpha particle passed straight through the gold atoms with their diffuse cloud of positive charge.
Rutherford modify the structure of the J J Thomson and he said that the positive charge concentrated at the centre is the nucleus and he said that nucleus at the centre which is consisting of the positive charge elements atomic particles and then the electrons are revolving around this nucleus
1914: Neil Bohr – Idea of Electronic shells
Energy given by atoms when heated had only specific amount of energy
So Electrons are orbitiing at the specific energy levels called the electronic Shells
1932: James Chadwick – Discovered Neutrones
Due to difference in mass of protons and the nucleus.
Structure of Atoms
Type of Sub Atomic Particle | Relative Charge | Relative mass | Position in the Atom |
Electron | -1 | 1/2000 | Around the nucleus in shells |
Proton | +1 | 1 | In the nucleus |
Neutron | 0 | 1 | In the nucleus |
No. of Proton, Neutron and Electron
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Electronic Configurations
Shell no. | I | II | III | IV |
Max no. of Electron | 2 | 8 | 8 | 18 |
For Example
Sodium = No. of electron =2,8,1
Magnesium = 2,8,2
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Element | Atomic Number | Configuration |
Hydrogen | 1 | 1 |
Helium | 2 | 2 |
Lithium | 3 | 2,1 |
Berylium | 4 | 2,2 |
Boron | 5 | 2,3 |
Carbon | 6 | 2,4 |
Nitrogen | 7 | 2,5 |
Oxygen | 8 | 2,6 |
Fluorine | 9 | 2,7 |
Iron | 10 | 2,8 |
Sodium | 11 | 2,8,1 |
Magnesium | 12 | 2,8,2 |
Aluminium | 13 | 2,8,3 |
Silicon | 14 | 2,8,4 |
Phosphorous | 15 | 2,8,5 |
Sulphur | 16 | 2,8,6 |
Chlorine | 17 | 2,8,7 |
Argon | 18 | 2,8,8 |
Potassium | 19 | 2,8,8,1 |
Sulphur | 20 | 2,8,8,2 |
Ions – Charged atoms – unequal no. of proton and Neutrons
Positive Ions – Loss of electrons
Negative Ions – Gain of electrons
More electron than proton
Atoms gain negative charge equal to the number of electrons gained
F– -1 charge as it has gained one electron
02- -2 charged as it has gained two electrons
11Na23 | Na+ | 8O16 | O2- | |
Proton | 11 | 11 | 8 | 8 |
Neutron | 12 | 12 | 8 | 8 |
Electron | 11 | 10 | 8 | 10 |
11Na23 | [13Al27]3+ | [8016]2- | |
Atomic number | 11 | 13 | 8 |
Mass Number | 23 | 27 | 16 |
Electron Number | 11 | 10 | 10 |
Proton Number | 11 | 13 | 8 |
Neutron Number | 12 | 14 | 8 |
Charge | 0 | +3 | -2 |
Electronic Configuration | 2,8,1 | 2,8 | 2,8 |
Basic Terms of Atomic Structure :
Q1 How to work out the neutron number of an atom ?
Mass number – Atomic Number
Q2 What do elements in the same group have in common ?
They have same number of electrons in the outermost shell. For example, Sodium, Potassium both group 1 has one electron in their outermost shells.
Q3 Why isotopes have similar chemical properties
Since they have equal number of electrons they have similar chemical properties.
Q4 Draw Structure of Calcium Atom
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I have tried my level best to cover the maximum of your specification. But this is not the alternative to the textbook. You should cover the specification or the textbook thoroughly. This is the quick revision to help you cover the gist of everything. In case you spot any errors then do let us know and we will rectify it.
References:
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